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Electronic structure and photophysics of a supermolecular iron complex having a long MLCT-state lifetime and panchromatic absorption

Exploiting earth-abundant iron-based metal complexes as high-performance photosensitizers demands long-lived electronically excited metal-to-ligand charge-transfer (MLCT) states, but these species suffer typically from femtosecond timescale charge-transfer (CT)-state quenching by low-lying nonreacti...

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Detalles Bibliográficos
Autores principales: Jiang, Ting, Bai, Yusong, Zhang, Peng, Han, Qiwei, Mitzi, David B., Therien, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: National Academy of Sciences 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7456135/
https://www.ncbi.nlm.nih.gov/pubmed/32788361
http://dx.doi.org/10.1073/pnas.2009996117