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Solvent Impact on the Diversity of Products in the Reaction of Lithium Diphenylphosphide and a Ti(III) Complex Supported by a tBu(2)P–P(SiMe(3)) Ligand
[Image: see text] We present two important trends in the reactivity of the titanium complex [(Me)NacNacTi(Cl){η(2)-P(SiMe(3))-PtBu(2)}] ((Me)NacNac(–) = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr(2)Ph) with nucleophilic reagents RLi (R = Ph(2)P, tBuO, (Me(3)Si)(2)N, and tBu(2)N) depending on the reaction...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7458418/ https://www.ncbi.nlm.nih.gov/pubmed/32799493 http://dx.doi.org/10.1021/acs.inorgchem.0c00824 |