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Solvent Impact on the Diversity of Products in the Reaction of Lithium Diphenylphosphide and a Ti(III) Complex Supported by a tBu(2)P–P(SiMe(3)) Ligand

[Image: see text] We present two important trends in the reactivity of the titanium complex [(Me)NacNacTi(Cl){η(2)-P(SiMe(3))-PtBu(2)}] ((Me)NacNac(–) = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr(2)Ph) with nucleophilic reagents RLi (R = Ph(2)P, tBuO, (Me(3)Si)(2)N, and tBu(2)N) depending on the reaction...

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Detalles Bibliográficos
Autores principales:	Ziółkowska, A., Szynkiewicz, N., Pikies, J., Ponikiewski, Ł.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2020
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7458418/ https://www.ncbi.nlm.nih.gov/pubmed/32799493 http://dx.doi.org/10.1021/acs.inorgchem.0c00824

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