Regiodivergent Hydroborative Ring Opening of Epoxides via Selective C–O Bond Activation

[Image: see text] A magnesium-catalyzed regiodivergent C–O bond cleavage protocol is presented. Readily available magnesium catalysts achieve the selective hydroboration of a wide range of epoxides and oxetanes yielding secondary and tertiary alcohols in excellent yields and regioselectivities. Expe...

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Detalles Bibliográficos
Autores principales: Magre, Marc, Paffenholz, Eva, Maity, Bholanath, Cavallo, Luigi, Rueping, Magnus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7458426/
https://www.ncbi.nlm.nih.gov/pubmed/32658463
http://dx.doi.org/10.1021/jacs.0c05917

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7458426/
https://www.ncbi.nlm.nih.gov/pubmed/32658463
http://dx.doi.org/10.1021/jacs.0c05917

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