Cargando…
Regiodivergent Hydroborative Ring Opening of Epoxides via Selective C–O Bond Activation
[Image: see text] A magnesium-catalyzed regiodivergent C–O bond cleavage protocol is presented. Readily available magnesium catalysts achieve the selective hydroboration of a wide range of epoxides and oxetanes yielding secondary and tertiary alcohols in excellent yields and regioselectivities. Expe...
Autores principales: | Magre, Marc, Paffenholz, Eva, Maity, Bholanath, Cavallo, Luigi, Rueping, Magnus |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7458426/ https://www.ncbi.nlm.nih.gov/pubmed/32658463 http://dx.doi.org/10.1021/jacs.0c05917 |
Ejemplares similares
-
s-Block Metal Catalysts for the Hydroboration
of Unsaturated Bonds
por: Magre, Marc, et al.
Publicado: (2022) -
Mechanistic insights into excited-state palladium catalysis for C–S bond formations and dehydrogenative sulfonylation of amines
por: Muralirajan, Krishnamoorthy, et al.
Publicado: (2023) -
Modulating stereoselectivity in allylic C(sp(3))-H bond arylations via nickel and photoredox catalysis
por: Huang, Long, et al.
Publicado: (2023) -
Ligand-controlled cobalt-catalyzed regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes
por: Wu, Caizhi, et al.
Publicado: (2020) -
(t)BuOLi-Promoted Hydroboration
of Esters and Epoxides
por: Shi, Yinyin, et al.
Publicado: (2022)