Impact of the Carbene Derivative Charge on the Decomposition Rates of Hoveyda–Grubbs-like Metathesis Catalysts

[Image: see text] Hoveyda–Grubbs metathesis catalysts undergo a relatively fast decomposition in the presence of olefins. Using a computational density functional theory approach, we show that positively charged derivatives of N-heterocyclic carbenes have little impact on the degradation/deactivatio...

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Detalles Bibliográficos
Autores principales: Jawiczuk, Magdalena, Marczyk, Anna, Młodzikowska-Pieńko, Katarzyna, Trzaskowski, Bartosz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7460089/
https://www.ncbi.nlm.nih.gov/pubmed/32639748
http://dx.doi.org/10.1021/acs.jpca.0c03096

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7460089/
https://www.ncbi.nlm.nih.gov/pubmed/32639748
http://dx.doi.org/10.1021/acs.jpca.0c03096

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