A Vinyl Cyclopropane Ring Expansion and Iridium‐Catalyzed Hydrogen Borrowing Cascade

A vinyl cyclopropane rearrangement embedded in an iridium‐catalyzed hydrogen borrowing reaction enabled the formation of substituted stereo‐defined cyclopentanes from Ph* methyl ketone and cyclopropyl alcohols. Mechanistic studies provide evidence for the ring‐expansion reaction being the result of...

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Detalles Bibliográficos
Autores principales: Wübbolt, Simon, Cheong, Choon Boon, Frost, James R., Christensen, Kirsten E., Donohoe, Timothy J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7463175/
https://www.ncbi.nlm.nih.gov/pubmed/32314851
http://dx.doi.org/10.1002/anie.202003614

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7463175/
https://www.ncbi.nlm.nih.gov/pubmed/32314851
http://dx.doi.org/10.1002/anie.202003614

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