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Synthesis of Poly(2-Acrylamido-2-Methylpropane Sulfonic Acid) and its Block Copolymers with Methyl Methacrylate and 2-Hydroxyethyl Methacrylate by Quasiliving Radical Polymerization Catalyzed by a Cyclometalated Ruthenium(II) Complex

The first example of quasiliving radical polymerization and copolymerization of 2-acrylamido-2-methylpropane sulfonic acid (AMPS) without previous protection of its strong acid groups catalyzed by [Ru(o-C(6)H(4)-2-py)(phen)(MeCN)(2)]PF(6) complex is reported. Nuclear magnetic resonance (RMN) and gel...

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Detalles Bibliográficos
Autores principales: Martínez-Cornejo, Vanessa, Velázquez-Roblero, Joaquin, Rosiles-González, Veronica, Correa-Duran, Monica, Avila-Ortega, Alejandro, Hernández-Núñez, Emanuel, Le Lagadec, Ronan, González-Díaz, Maria Ortencia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7464165/
https://www.ncbi.nlm.nih.gov/pubmed/32726922
http://dx.doi.org/10.3390/polym12081663