A Leopard Cannot Change Its Spots: Unexpected Products from the Vilsmeier Reaction on 5,10,15-Tritolylcorrole

The reaction of 5,10,15-tritolylcorrole with 3-dimethylaminoacrolein (3-DMA) and POCl(3) gives a further example of the rebel reactivity of this contracted macrocycle. While no evidence was obtained for the formation of the expected β-acrolein corrole, the inner core substituted N21,N22-3-formylprop...

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Detalles Bibliográficos
Autores principales: Caroleo, Fabrizio, Petrella, Greta, Di Zazzo, Lorena, Nardis, Sara, Berionni Berna, Beatrice, Cicero, Daniel O., Paolesse, Roberto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7464667/
https://www.ncbi.nlm.nih.gov/pubmed/32781720
http://dx.doi.org/10.3390/molecules25163583

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7464667/
https://www.ncbi.nlm.nih.gov/pubmed/32781720
http://dx.doi.org/10.3390/molecules25163583

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