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Total Synthesis Provides Strong Evidence: Xestocyclamine A is the Enantiomer of Ingenamine
[Image: see text] Xestocyclamine A ((−)-1) is featured prominently in a biosynthesis pathway leading to a large family of polycyclic alkaloids. The first total synthesis now proves that the structure of this compound had originally been misassigned. The route to (−)-1 is based on a double Michael ad...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7467676/ https://www.ncbi.nlm.nih.gov/pubmed/32544329 http://dx.doi.org/10.1021/jacs.0c05347 |