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Computational Study on the Boundary Between the Concerted and Stepwise Mechanism of Bimolecular S(N)Ar Reactions
[Image: see text] The text-book mechanism of bimolecular nucleophilic aromatic substitutions (S(N)Ar) reactions is a stepwise process that proceeds via a so-called Meisenheimer intermediate. Only recently the alternative, concerted version of this mechanism has gained acceptance as more and more exa...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7472429/ https://www.ncbi.nlm.nih.gov/pubmed/32786763 http://dx.doi.org/10.1021/jacs.0c01975 |