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Synthesis by deamination reaction and crystal structure at 120 K of (16Z,19E)-18-oxo-N-(pyridin-2-yl)-6,7,9,10-tetra­hydro-18H-dibenzo[h,o][1,4,7]trioxa­cyclo­hexa­decine-17-carboxamide

The title compound, C(27)H(24)N(2)O(5), is a product of the deamination reaction from aza-14-crown-4 ether containing the γ-piperidone subunit. The title mol­ecule contains a 16-membered macrocycle with the conformation of the C—O—C—C—O—C—C—O—C polyether chain being t–g ((-))–t–t–g ((+))–t (t = tran...

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Detalles Bibliográficos
Autores principales: Wodajo, Ayalew T., Tran, Thi Thanh Van, Truong, Hong Hieu, Tskhovrebov, Alexander G., Le, The Duan, Khrustalev, Victor N., Le, Tuan Anh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7472769/
https://www.ncbi.nlm.nih.gov/pubmed/32939299
http://dx.doi.org/10.1107/S2056989020010968