Anomalous chemically induced electron spin polarization in proton-coupled electron transfer reactions: insight into radical pair dynamics

Time-resolved electron paramagnetic resonance (TREPR) spectroscopy has been used to study the proton coupled electron transfer (PCET) reaction between a ruthenium complex (Ru(bpz)(bpy)(2)) and several substituted hydroquinones (HQ). After excitation at 355 nm, the HQ moiety forms a strong hydrogen b...

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Detalles Bibliográficos
Autores principales: Brugh, Alexander M., Forbes, Malcolm D. E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7480077/
https://www.ncbi.nlm.nih.gov/pubmed/32953022
http://dx.doi.org/10.1039/d0sc02691c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7480077/
https://www.ncbi.nlm.nih.gov/pubmed/32953022
http://dx.doi.org/10.1039/d0sc02691c

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