Concerted aryl-sulfur reductive elimination from PNP pincer-supported Co(iii) and subsequent Co(i)/Co(iii) comproportionation

This report discloses a combined experimental and computational study aimed at understanding C–S reductive elimination from Co(iii) supported by a diarylamido/bis(phosphine) PNP pincer ligand. Divalent (PNP)Co-aryl complexes could be easily oxidized to five-coordinate Co(iii) derivatives, and anion...

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Detalles Bibliográficos
Autores principales: Foley, Bryan J., Palit, Chandra Mouli, Bhuvanesh, Nattamai, Zhou, Jia, Ozerov, Oleg V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7480512/
https://www.ncbi.nlm.nih.gov/pubmed/32953010
http://dx.doi.org/10.1039/d0sc01813a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7480512/
https://www.ncbi.nlm.nih.gov/pubmed/32953010
http://dx.doi.org/10.1039/d0sc01813a

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