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Selective Oxidation by H(5)[PV(2)Mo(10)O(40)] in a Highly Acidic Medium
[Image: see text] Dissolution of the polyoxometalate (POM) cluster anion H(5)[PV(2)Mo(10)O(40)] (1; a mixture of positional isomers) in 50% aq H(2)SO(4) dramatically enhances its ability to oxidize methylarenes, while fully retaining the high selectivities typical of this versatile oxidant. To bette...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7482320/ https://www.ncbi.nlm.nih.gov/pubmed/32134633 http://dx.doi.org/10.1021/acs.inorgchem.9b03747 |