Cargando…

Selective Oxidation by H(5)[PV(2)Mo(10)O(40)] in a Highly Acidic Medium

[Image: see text] Dissolution of the polyoxometalate (POM) cluster anion H(5)[PV(2)Mo(10)O(40)] (1; a mixture of positional isomers) in 50% aq H(2)SO(4) dramatically enhances its ability to oxidize methylarenes, while fully retaining the high selectivities typical of this versatile oxidant. To bette...

Descripción completa

Detalles Bibliográficos
Autores principales: Tiwari, Chandan Kumar, Baranov, Mark, Neyman, Alevtina, Neumann, Ronny, Weinstock, Ira A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7482320/
https://www.ncbi.nlm.nih.gov/pubmed/32134633
http://dx.doi.org/10.1021/acs.inorgchem.9b03747