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Pd-Catalyzed Enantioselective Hydroalkynylation of Cyclopropenes
[Image: see text] We report herein an easy, mild, and robust Pd-catalyzed enantioselective hydroalkynylation reaction of achiral cyclopropenes. Commercially available Pd(acac)(2) and (R)-DM-BINAP proved to be the best combination to reach high diastereo- and enantioselectivities.
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7493299/ https://www.ncbi.nlm.nih.gov/pubmed/32953232 http://dx.doi.org/10.1021/acscatal.9b04960 |