4-Dimethylaminopyridine-Catalyzed Metal-Free Aerobic Oxidation of Aryl α-Halo Esters to Aryl α-Keto Esters

[Image: see text] A novel, metal-free aerobic oxidation method is described. 4-Dimethylaminopyridine (DMAP) successfully catalyzed the oxidation of aryl α-halo esters to corresponding aryl α-keto esters (up to 95% yield) under mild reaction conditions (Li(2)CO(3), dimethylacetamide, air, and room te...

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Detalles Bibliográficos
Autores principales: Jung, Yeonghun, Hong, Jee Eun, Baek, Seung Tae, Hong, Suckchang, Kwak, Jae-Hwan, Park, Yohan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7495759/
https://www.ncbi.nlm.nih.gov/pubmed/32954144
http://dx.doi.org/10.1021/acsomega.0c02511

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7495759/
https://www.ncbi.nlm.nih.gov/pubmed/32954144
http://dx.doi.org/10.1021/acsomega.0c02511

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