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Solvent Dependence of the Monomer–Dimer Equilibrium of Ketone‐Substituted Triscatecholate Titanium(IV) Complexes

Hierarchical helicates based on ketone‐substituted titanium(IV)triscatecholates show different monomer‐dimer behavior depending on different solvents. The dimerization constants of a whole series of differently alkyl‐substituted complexes is analyzed to show that the solvent has a very strong influe...

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Detalles Bibliográficos
Autores principales: Kwamen, A. Carel N., Jenniches, Judith, Oppel, Iris M., Albrecht, Markus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496165/
https://www.ncbi.nlm.nih.gov/pubmed/32222003
http://dx.doi.org/10.1002/chem.202001053