Nanoscale Organolanthanum Clusters: Nuclearity‐Directing Role of Cyclopentadienyl and Halogenido Ligands

Tetramethylaluminato/halogenido(X) ligand exchange reactions in half‐sandwich complexes [Cp(R)La(AlMe(4))(2)] are feasible in non‐coordinating solvents and provide access to large coordination clusters of the type [Cp(R)LaX(2)](x). Incomplete exchange reactions generate the hexalanthanum clusters [C...

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Detalles Bibliográficos
Autores principales: Buschmann, Dennis A., Dietrich, H. Martin, Schneider, David, Birkelbach, Verena M., Stuhl, Christoph, Törnroos, Karl W., Maichle‐Mössmer, Cäcilia, Anwander, Reiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496188/
https://www.ncbi.nlm.nih.gov/pubmed/32329535
http://dx.doi.org/10.1002/chem.202001482

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496188/
https://www.ncbi.nlm.nih.gov/pubmed/32329535
http://dx.doi.org/10.1002/chem.202001482

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