Unexpected Vulnerability of DPEphos to C−O Activation in the Presence of Nucleophilic Metal Hydrides

C−O bond activation of DPEphos occurs upon mild heating in the presence of [Ru(NHC)(2)(PPh(3))(2)H(2)] (NHC=N‐heterocyclic carbene) to form phosphinophenolate products. When NHC=IEt(2)Me(2), C−O activation is accompanied by C−N activation of an NHC ligand to yield a coordinated N‐phosphino‐functiona...

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Detalles Bibliográficos
Autores principales: Cybulski, Mateusz K., Beattie, Nicholas A., Macgregor, Stuart A., Mahon, Mary F., Whittlesey, Michael K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496192/
https://www.ncbi.nlm.nih.gov/pubmed/32428278
http://dx.doi.org/10.1002/chem.202001685

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496192/
https://www.ncbi.nlm.nih.gov/pubmed/32428278
http://dx.doi.org/10.1002/chem.202001685

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