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Unexpected Vulnerability of DPEphos to C−O Activation in the Presence of Nucleophilic Metal Hydrides
C−O bond activation of DPEphos occurs upon mild heating in the presence of [Ru(NHC)(2)(PPh(3))(2)H(2)] (NHC=N‐heterocyclic carbene) to form phosphinophenolate products. When NHC=IEt(2)Me(2), C−O activation is accompanied by C−N activation of an NHC ligand to yield a coordinated N‐phosphino‐functiona...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496192/ https://www.ncbi.nlm.nih.gov/pubmed/32428278 http://dx.doi.org/10.1002/chem.202001685 |