Zirconium‐Catalyzed Atom‐Economical Synthesis of 1,1‐Diborylalkanes from Terminal and Internal Alkenes

A general and atom‐economical synthesis of 1,1‐diborylalkanes from alkenes and a borane without the need for an additional H(2) acceptor is reported for the first time. The key to our success is the use of an earth‐abundant zirconium‐based catalyst, which allows a balance of self‐contradictory react...

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Detalles Bibliográficos
Autores principales: Wang, Xianjin, Cui, Xin, Li, Sida, Wang, Yue, Xia, Chungu, Jiao, Haijun, Wu, Lipeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496309/
https://www.ncbi.nlm.nih.gov/pubmed/32297413
http://dx.doi.org/10.1002/anie.202002642

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496309/
https://www.ncbi.nlm.nih.gov/pubmed/32297413
http://dx.doi.org/10.1002/anie.202002642

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