Filling a Gap: The Coordinatively Saturated Group 4 Carbonyl Complexes TM(CO)(8) (TM=Zr, Hf) and Ti(CO)(7)

Homoleptic Group 4 metal carbonyl cation and neutral complexes were prepared in the gas phase and/or in solid neon matrix. Infrared spectroscopy studies reveal that both zirconium and hafnium form eight‐coordinate carbonyl neutral and cation complexes. In contrast, titanium forms only the six‐coordi...

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Detalles Bibliográficos
Autores principales: Deng, Guohai, Lei, Shujun, Pan, Sudip, Jin, Jiaye, Wang, Guanjun, Zhao, Lili, Zhou, Mingfei, Frenking, Gernot
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496348/
https://www.ncbi.nlm.nih.gov/pubmed/32191361
http://dx.doi.org/10.1002/chem.201905552