Filling a Gap: The Coordinatively Saturated Group 4 Carbonyl Complexes TM(CO)(8) (TM=Zr, Hf) and Ti(CO)(7)
Homoleptic Group 4 metal carbonyl cation and neutral complexes were prepared in the gas phase and/or in solid neon matrix. Infrared spectroscopy studies reveal that both zirconium and hafnium form eight‐coordinate carbonyl neutral and cation complexes. In contrast, titanium forms only the six‐coordi...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496348/ https://www.ncbi.nlm.nih.gov/pubmed/32191361 http://dx.doi.org/10.1002/chem.201905552 |