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Engineering Crystals Using sp(3)‐C Centred Tetrel Bonding Interactions

1,1,2,2‐Tetracyanocyclopropane derivatives 1 and 2 were designed and synthesized to probe the utility of sp(3)‐C centred tetrel bonding interactions in crystal engineering. The crystal packing of 1 and 2 and their 1,4‐dioxane cocrystals is dominated by sp(3)‐C(CN)(2)⋅⋅⋅O interactions, has significan...

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Detalles Bibliográficos
Autores principales: Roeleveld, Julius J., Lekanne Deprez, Siebe J., Verhoofstad, Abraham, Frontera, Antonio, van der Vlugt, Jarl Ivar, Mooibroek, Tiddo Jonathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496358/
https://www.ncbi.nlm.nih.gov/pubmed/32557861
http://dx.doi.org/10.1002/chem.202002613