Photoinduced and Thermal Single‐Electron Transfer to Generate Radicals from Frustrated Lewis Pairs

Archetypal phosphine/borane frustrated Lewis pairs (FLPs) are famed for their ability to activate small molecules. The mechanism is generally believed to involve two‐electron processes. However, the detection of radical intermediates indicates that single‐electron transfer (SET) generating frustrate...

Descripción completa

Detalles Bibliográficos
Autores principales: Holtrop, Flip, Jupp, Andrew R., van Leest, Nicolaas P., Paradiz Dominguez, Maximilian, Williams, René M., Brouwer, Albert M., de Bruin, Bas, Ehlers, Andreas W., Slootweg, J. Chris
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496419/
https://www.ncbi.nlm.nih.gov/pubmed/32259331
http://dx.doi.org/10.1002/chem.202001494

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496419/
https://www.ncbi.nlm.nih.gov/pubmed/32259331
http://dx.doi.org/10.1002/chem.202001494

Ejemplares similares