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Photoinduced and Thermal Single‐Electron Transfer to Generate Radicals from Frustrated Lewis Pairs
Archetypal phosphine/borane frustrated Lewis pairs (FLPs) are famed for their ability to activate small molecules. The mechanism is generally believed to involve two‐electron processes. However, the detection of radical intermediates indicates that single‐electron transfer (SET) generating frustrate...
Autores principales: | Holtrop, Flip, Jupp, Andrew R., van Leest, Nicolaas P., Paradiz Dominguez, Maximilian, Williams, René M., Brouwer, Albert M., de Bruin, Bas, Ehlers, Andreas W., Slootweg, J. Chris |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496419/ https://www.ncbi.nlm.nih.gov/pubmed/32259331 http://dx.doi.org/10.1002/chem.202001494 |
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