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Reduced Arene Complexes of Scandium

Alkali metal naphthalenide or anthracenide reacted with scandium(III) anilides [Sc(X){N(tBu)Xy}(2)(thf)] (X=N(tBu)Xy (1); X=Cl (2); Xy=C(6)H(3)‐3,5‐Me(2)) to give scandium complexes [M(thf)(n)][Sc{N(tBu)Xy}(2)(RA)] (M=Li–K; n=1–6; RA=C(10)H(8) (2−) (3‐Naph‐K) and C(14)H(10) (2−) (3‐Anth‐M)) containi...

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Detalles Bibliográficos
Autores principales: Ghana, Priyabrata, Hoffmann, Alexander, Spaniol, Thomas P., Okuda, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496515/
https://www.ncbi.nlm.nih.gov/pubmed/32160350
http://dx.doi.org/10.1002/chem.202000946