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Surface Charges at the CaF(2)/Water Interface Allow Very Fast Intermolecular Vibrational‐Energy Transfer

We investigate the dynamics of water in contact with solid calcium fluoride, where at low pH, localized charges can develop upon fluorite dissolution. We use 2D surface‐specific vibrational spectroscopy to quantify the heterogeneity of the interfacial water (D(2)O) molecules and provide information...

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Detalles Bibliográficos
Autores principales: Lesnicki, Dominika, Zhang, Zhen, Bonn, Mischa, Sulpizi, Marialore, Backus, Ellen H. G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496624/
https://www.ncbi.nlm.nih.gov/pubmed/32239715
http://dx.doi.org/10.1002/anie.202004686