d–d Dative Bonding Between Iron and the Alkaline‐Earth Metals Calcium, Strontium, and Barium

Double deprotonation of the diamine 1,1′‐(tBuCH(2)NH)‐ferrocene (1‐H(2)) by alkaline‐earth (Ae) or Eu(II) metal reagents gave the complexes 1‐Ae (Ae=Mg, Ca, Sr, Ba) and 1‐Eu. 1‐Mg crystallized as a monomer while the heavier complexes crystallized as dimers. The Fe⋅⋅⋅Mg distance in 1‐Mg is too long f...

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Detalles Bibliográficos
Autores principales: Stegner, Philipp, Färber, Christian, Oetzel, Jan, Siemeling, Ulrich, Wiesinger, Michael, Langer, Jens, Pan, Sudip, Holzmann, Nicole, Frenking, Gernot, Albold, Uta, Sarkar, Biprajit, Harder, Sjoerd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496664/
https://www.ncbi.nlm.nih.gov/pubmed/32463527
http://dx.doi.org/10.1002/anie.202005774

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496664/
https://www.ncbi.nlm.nih.gov/pubmed/32463527
http://dx.doi.org/10.1002/anie.202005774

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