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Modular Synthesis of Furans with up to Four Different Substituents by a trans‐Carboboration Strategy
Propargyl alcohols, on treatment with MHMDS (M=Na, K), B(2)(pin)(2), an acid chloride and a palladium/copper co‐catalyst system, undergo a reaction cascade comprised of trans‐diboration, regioselective acylation, cyclization and dehydration to give trisubstituted furylboronic acid pinacol ester deri...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496670/ https://www.ncbi.nlm.nih.gov/pubmed/32374441 http://dx.doi.org/10.1002/anie.202005560 |