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Long‐Lived Charge‐Transfer State Induced by Spin‐Orbit Charge Transfer Intersystem Crossing (SOCT‐ISC) in a Compact Spiro Electron Donor/Acceptor Dyad

We prepared conceptually novel, fully rigid, spiro compact electron donor (Rhodamine B, lactam form, RB)/acceptor (naphthalimide; NI) orthogonal dyad to attain the long‐lived triplet charge‐transfer ((3)CT) state, based on the electron spin control using spin‐orbit charge transfer intersystem crossi...

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Detalles Bibliográficos
Autores principales: Liu, Dongyi, El‐Zohry, Ahmed M., Taddei, Maria, Matt, Clemens, Bussotti, Laura, Wang, Zhijia, Zhao, Jianzhang, Mohammed, Omar F., Di Donato, Mariangela, Weber, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496792/
https://www.ncbi.nlm.nih.gov/pubmed/32270586
http://dx.doi.org/10.1002/anie.202003560