Heavy‐Atom Tunneling in Semibullvalenes: How Driving Force, Substituents, and Environment Influence the Tunneling Rates

The Cope rearrangement of selectively deuterated isotopomers of 1,5‐dimethylsemibullvalene 2 a and 3,7‐dicyano‐1,5‐dimethylsemibullvalene 2 b were studied in cryogenic matrices. In both semibullvalenes the Cope rearrangement is governed by heavy‐atom tunneling. The driving force for the rearrangemen...

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Detalles Bibliográficos
Autores principales: Schleif, Tim, Tatchen, Jörg, Rowen, Julien F., Beyer, Frederike, Sanchez‐Garcia, Elsa, Sander, Wolfram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496793/
https://www.ncbi.nlm.nih.gov/pubmed/32293763
http://dx.doi.org/10.1002/chem.202001202

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496793/
https://www.ncbi.nlm.nih.gov/pubmed/32293763
http://dx.doi.org/10.1002/chem.202001202

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