Cargando…
Heavy‐Atom Tunneling in Semibullvalenes: How Driving Force, Substituents, and Environment Influence the Tunneling Rates
The Cope rearrangement of selectively deuterated isotopomers of 1,5‐dimethylsemibullvalene 2 a and 3,7‐dicyano‐1,5‐dimethylsemibullvalene 2 b were studied in cryogenic matrices. In both semibullvalenes the Cope rearrangement is governed by heavy‐atom tunneling. The driving force for the rearrangemen...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496793/ https://www.ncbi.nlm.nih.gov/pubmed/32293763 http://dx.doi.org/10.1002/chem.202001202 |