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Synthesis and Characterization of the Highly Unstable Metalloid Cluster Ag(64)(P(n)Bu(3))(16)Cl(6)
The reduction of ((n)Bu(3)P)AgCl with LiBH((s)Bu)(3) in toluene gives the metalloid silver cluster Ag(64)(P(n)Bu(3))(16)Cl(6) (1) as dark red, temperature‐ and light‐sensitive single crystals in high yield. 1 is the largest structurally characterized metalloid silver cluster exhibiting chlorine and...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496867/ https://www.ncbi.nlm.nih.gov/pubmed/32453467 http://dx.doi.org/10.1002/anie.202006454 |