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Synthesis and Characterization of the Highly Unstable Metalloid Cluster Ag(64)(P(n)Bu(3))(16)Cl(6)

The reduction of ((n)Bu(3)P)AgCl with LiBH((s)Bu)(3) in toluene gives the metalloid silver cluster Ag(64)(P(n)Bu(3))(16)Cl(6) (1) as dark red, temperature‐ and light‐sensitive single crystals in high yield. 1 is the largest structurally characterized metalloid silver cluster exhibiting chlorine and...

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Detalles Bibliográficos
Autores principales:	Diecke, Maximilian, Schrenk, Claudio, Schnepf, Andreas
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7496867/ https://www.ncbi.nlm.nih.gov/pubmed/32453467 http://dx.doi.org/10.1002/anie.202006454

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