Oxidation, Coordination, and Nickel‐Mediated Deconstruction of a Highly Electron‐Rich Diboron Analogue of 1,3,5‐Hexatriene

The reductive coupling of an N‐heterocyclic carbene (NHC) stabilized (dibromo)vinylborane yields a 1,2‐divinyldiborene, which, although isoelectronic to a 1,3,5‐triene, displays no extended π conjugation because of twisting of the C(2)B(2)C(2) chain. While this divinyldiborene coordinates to copper(...

Descripción completa

Detalles Bibliográficos
Autores principales: Hermann, Alexander, Fantuzzi, Felipe, Arrowsmith, Merle, Zorn, Theresa, Krummenacher, Ivo, Ritschel, Benedikt, Radacki, Krzysztof, Engels, Bernd, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497145/
https://www.ncbi.nlm.nih.gov/pubmed/32449598
http://dx.doi.org/10.1002/anie.202006131

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497145/
https://www.ncbi.nlm.nih.gov/pubmed/32449598
http://dx.doi.org/10.1002/anie.202006131

Ejemplares similares