Cargando…

Oxidation, Coordination, and Nickel‐Mediated Deconstruction of a Highly Electron‐Rich Diboron Analogue of 1,3,5‐Hexatriene

The reductive coupling of an N‐heterocyclic carbene (NHC) stabilized (dibromo)vinylborane yields a 1,2‐divinyldiborene, which, although isoelectronic to a 1,3,5‐triene, displays no extended π conjugation because of twisting of the C(2)B(2)C(2) chain. While this divinyldiborene coordinates to copper(...

Descripción completa

Detalles Bibliográficos
Autores principales:	Hermann, Alexander, Fantuzzi, Felipe, Arrowsmith, Merle, Zorn, Theresa, Krummenacher, Ivo, Ritschel, Benedikt, Radacki, Krzysztof, Engels, Bernd, Braunschweig, Holger
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497145/ https://www.ncbi.nlm.nih.gov/pubmed/32449598 http://dx.doi.org/10.1002/anie.202006131

Ejemplares similares

Reduction and Rearrangement of a Boron(I) Carbonyl Complex
por: Rang, Maximilian, et al.
Publicado: (2020)

Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
por: Hagspiel, Stephan, et al.
Publicado: (2019)

Platinum‐Templated Coupling of B=N Units: Synthesis of BNBN Analogues of 1,3‐Dienes and a Butatriene
por: Brunecker, Carina, et al.
Publicado: (2021)

A Neutral Beryllium(I) Radical
por: Czernetzki, Corinna, et al.
Publicado: (2021)

Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species
por: Dhara, Debabrata, et al.
Publicado: (2022)

Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity
por: Hagspiel, Stephan, et al.
Publicado: (2021)

Multiple responses of 1,6-diphenyl-1,3,5-hexatriene to mechanical stimulation: emission enhancement, piezochromism and negative linear compressibility
por: Fu, Zhiyuan, et al.
Publicado: (2023)

cAAC‐Stabilized 9,10‐diboraanthracenes—Acenes with Open‐Shell Singlet Biradical Ground States
por: Saalfrank, Christian, et al.
Publicado: (2020)

B(MIDA)-Containing Diborons
por: Yoshida, Hiroto, et al.
Publicado: (2017)

Isolation of Neutral, Mono‐, and Dicationic B(2)P(2) Rings by Diphosphorus Addition to a Boron−Boron Triple Bond
por: Brückner, Tobias, et al.
Publicado: (2021)

Modulation of the Naked‐Eye and Fluorescence Color of a Protonated Boron‐Doped Thiazolothiazole by Anion‐Dependent Hydrogen Bonding
por: Hagspiel, Stephan, et al.
Publicado: (2022)

Synthesis and reduction chemistry of mixed-Lewis-base-stabilised chloroborylenes
por: Arrowsmith, Merle, et al.
Publicado: (2019)

Highly Colored Boron‐Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates
por: Hagspiel, Stephan, et al.
Publicado: (2021)

Boroles from alumoles: accessing boroles with alkyl-substituted backbones via transtrielation
por: Bohlen, Josina L., et al.
Publicado: (2023)

Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame Complexes
por: Brunecker, Carina, et al.
Publicado: (2020)

Boron‐ versus Nitrogen‐Centered Nucleophilic Reactivity of (Cyano)hydroboryl Anions: Synthesis of Cyano(hydro)organoboranes and 2‐Aza‐1,4‐diborabutatrienes
por: Gärtner, Annalena, et al.
Publicado: (2021)

Super electron donors derived from diboron
por: Zhang, Li, et al.
Publicado: (2018)

Deconstructing Protein Binding of Sulfonamides and Sulfonamide Analogues
por: Purder, Patrick L., et al.
Publicado: (2023)

Isolation and Reactivity of an Antiaromatic s‐Block Metal Compound
por: Roy, Dipak Kumar, et al.
Publicado: (2020)

Recent Progress in Diboronic-Acid-Based Glucose Sensors
por: Nan, Ke, et al.
Publicado: (2023)

Diboramacrocycles: reversible borole dimerisation–dissociation systems
por: Fuchs, Sonja, et al.
Publicado: (2022)

Rhodium‐Mediated Stoichiometric Synthesis of Mono‐, Bi‐, and Bis‐1,2‐Azaborinines: 1‐Rhoda‐3,2‐azaboroles as Reactive Precursors
por: Heß, Merlin, et al.
Publicado: (2021)

Unsymmetrical Diboron Reagents: Application in Borylation Reactions of Unsaturated Bonds
por: Ding, Siyi, et al.
Publicado: (2019)

Aromatic Diboronic Acids as Effective KPC/AmpC Inhibitors
por: Krajewska, Joanna, et al.
Publicado: (2023)

Coligand role in the NHC nickel catalyzed C–F bond activation: investigations on the insertion of bis(NHC) nickel into the C–F bond of hexafluorobenzene
por: Kuntze-Fechner, Maximilian W., et al.
Publicado: (2020)

One- and two-electron reduction of triarylborane-based helical donor–acceptor compounds
por: Jia, Xiangqing, et al.
Publicado: (2021)

(2-Methoxy-1,3-phenylene)diboronic acid
por: Dąbrowski, Marek, et al.
Publicado: (2008)

Polycationic Redox‐Active Cyclophanes with Integrated Electron‐Rich Diboron Units
por: Filbeck, Erik, et al.
Publicado: (2021)

Planar Four-Membered Diboron Actinide Compound with Double Möbius Aromaticity
por: Lin, Xuhui, et al.
Publicado: (2023)

Tuning phenoxyl-substituted diketopyrrolopyrroles from quinoidal to biradical ground states through (hetero-)aromatic linkers
por: Rausch, Rodger, et al.
Publicado: (2020)

Self-Assembly of Diboronic Esters with U-Shaped Bipyridines: “Plug-in-Socket” Assemblies
por: Hartwick, Christopher J., et al.
Publicado: (2021)

Palladium-catalyzed hydroboration reaction of unactivated alkynes with bis (pinacolato) diboron in water
por: Yang, Ming, et al.
Publicado: (2022)

Diboronate Fluorophore for the Measurement of l-Glucose and Other Carbohydrates and Its Interaction with Albumin
por: Solomos, Konstantinos, et al.
Publicado: (2022)

Substituent engineering of the diboron molecular architecture for a nondoped and ultrathin emitting layer
por: Wu, Tien-Lin, et al.
Publicado: (2022)

Copper-Catalyzed Borylation of Styrenes by 1,8-Diaminonaphthalene-Protected Diboronic Acid
por: Yasuda, Taiga, et al.
Publicado: (2023)

Copper-Catalyzed Diboron-Mediated cis-Semi-Hydrogenation of Alkynes under Facile Conditions
por: Zeng, Yuxi, et al.
Publicado: (2022)

Diboronic-Acid-Based Electrochemical Sensor for Enzyme-Free Selective and Sensitive Glucose Detection
por: Kim, Joong-Hyun, et al.
Publicado: (2023)

Nickel boryl complexes and nickel-catalyzed alkyne borylation
por: Tendera, Lukas, et al.
Publicado: (2023)

Metal‐Free Intermolecular C−H Borylation of N‐Heterocycles at B−B Multiple Bonds
por: Brückner, Tobias, et al.
Publicado: (2022)

Stereoselective Diels–Alder Reactions of gem-Diborylalkenes: Toward the Synthesis of gem-Diboron-Based Polymers
por: Eghbarieh, Nadim, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_1tkdg6gm0do5fr6qkthj2c5hmd