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Electrochemical Iodine‐Mediated Oxidation of Enamino‐Esters to 2H‐Azirine‐2‐Carboxylates Supported by Design of Experiments

An electrochemical iodine‐mediated transformation of enamino‐esters for the synthesis of 2H‐azirine‐2‐carboxylates is presented. In addition, a thermic conversion of azirines to 4‐carboxy‐oxazoles in quantitative yield without purification was described. Both classes 2H‐azirines‐2‐carboxylates and t...

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Detalles Bibliográficos
Autores principales: Babaoglu, Emre, Hilt, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497194/
https://www.ncbi.nlm.nih.gov/pubmed/32220135
http://dx.doi.org/10.1002/chem.202001465