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Hydroalkylation of Aryl Alkenes with Organohalides Catalyzed by Molybdenum Oxido Based Lewis Pairs

Three molybdenum(VI) dioxido complexes [MoO(2)(L)(2)] bearing Schiff base ligands were reacted with B(C(6)F(5))(3) to afford the corresponding adducts [MoO{OB(C(6)F(5))(3)}(L)(2)], which were fully characterized. They exhibit Frustrated Lewis‐Pairs reactivity when reacting with silanes. Especially,...

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Detalles Bibliográficos
Autores principales: Zwettler, Niklas, Dupé, Antoine, Klokić, Sumea, Milinković, Angela, Rodić, Dado, Walg, Simon, Neshchadin, Dmytro, Belaj, Ferdinand, Mösch‐Zanetti, Nadia C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497237/
https://www.ncbi.nlm.nih.gov/pubmed/32982624
http://dx.doi.org/10.1002/adsc.202000425