Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes

Herein we describe the first examples of isolable electron‐precise diboranes(4) that bear azide moieties: the acyclic 1,2‐diazido‐1,2‐bis(dimethylamino)diborane(4) and the cyclic 1,4‐diaryl‐2,3‐diazido‐1,4‐diaza‐2,3‐diborinines (aryl=mesityl, 2,6‐xylyl, 4‐tolyl). The reported examples are not only s...

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Detalles Bibliográficos
Autores principales: Thiess, Torsten, Bélanger‐Chabot, Guillaume, Fantuzzi, Felipe, Michel, Maximilian, Ernst, Moritz, Engels, Bernd, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497274/
https://www.ncbi.nlm.nih.gov/pubmed/32270577
http://dx.doi.org/10.1002/anie.202003050

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497274/
https://www.ncbi.nlm.nih.gov/pubmed/32270577
http://dx.doi.org/10.1002/anie.202003050

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