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Asymmetric Synthesis of [2.2.2]-Bicyclic Lactones via All-Carbon Inverse-Electron-Demand Diels–Alder Reaction

[Image: see text] In this paper, a new cycloaddition between α,β-unsaturated aldehydes and coumalates realized under dienamine activation has been described. The reaction proceeds regioselectively with the distal double bond of the dienamine system acting as electron-rich dienophile. It leads to the...

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Detalles Bibliográficos
Autores principales: Saktura, Maciej, Grzelak, Paulina, Dybowska, Joanna, Albrecht, Łukasz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7497662/
https://www.ncbi.nlm.nih.gov/pubmed/32065757
http://dx.doi.org/10.1021/acs.orglett.0c00138