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An Electrochemical Approach toward the Metastable Type II Clathrate Germanium Allotrope
[Image: see text] By using an anodic conversion process at 280 °C, the type II clathrates Na(1.7(6))Ge(136) and Na(23.0(5))Ge(136) were obtained from Na(12)Ge(17) as the starting material. An alkali-metal iodide molten-salt electrolyte complied with the reaction conditions, allowing for the formatio...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7498141/ https://www.ncbi.nlm.nih.gov/pubmed/32833439 http://dx.doi.org/10.1021/acs.inorgchem.0c01796 |