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A SF(5) Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes
The synthesis of the triarylphosphine, P(p-C(6)H(4)SF(5))(3) containing a SF(5) group, has been achieved. The experimental and theoretical studies showed that P(p-C(6)H(4)SF(5))(3) is a weaker σ-donor when compared with other substituted triarylphosphines, which is consistent with the electron-withd...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7504798/ https://www.ncbi.nlm.nih.gov/pubmed/32882799 http://dx.doi.org/10.3390/molecules25173977 |