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A SF(5) Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes

The synthesis of the triarylphosphine, P(p-C(6)H(4)SF(5))(3) containing a SF(5) group, has been achieved. The experimental and theoretical studies showed that P(p-C(6)H(4)SF(5))(3) is a weaker σ-donor when compared with other substituted triarylphosphines, which is consistent with the electron-withd...

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Detalles Bibliográficos
Autores principales:	Talavera, Maria, Hinze, Silke, Braun, Thomas, Laubenstein, Reik, Herrmann, Roy
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7504798/ https://www.ncbi.nlm.nih.gov/pubmed/32882799 http://dx.doi.org/10.3390/molecules25173977

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