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Palladium-catalyzed dearomative 1,4-difunctionalization of naphthalenes

A highly diastereoselective dearomatization of naphthalenes via a Pd-catalyzed 1,4-difunctionalization reaction is described. In the presence of a commercially available palladium precursor and ligand, intramolecular dearomative Heck-type insertion provides π-allylpalladium intermediates which are r...

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Detalles Bibliográficos
Autores principales: Yang, Ping, Zheng, Chao, Nie, Yu-Han, You, Shu-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7504896/
https://www.ncbi.nlm.nih.gov/pubmed/33033598
http://dx.doi.org/10.1039/d0sc02816a