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Optically Pure Aziridin-2-yl Methanols as Readily Available (1)H NMR Sensors for Enantiodiscrimination of α-Racemic Carboxylic Acids Containing Tertiary or Quaternary Stereogenic Centers
[Image: see text] Enantiopure aziridin-2-yl methanols 3–7 are used as highly effective sensors for enantiodiscrimination of α-racemic carboxylic acids containing tertiary or quaternary stereogenic centers. A linear correlation between theoretical and observed % ee values for CSA-3 and enantiomerical...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7506949/ https://www.ncbi.nlm.nih.gov/pubmed/32805106 http://dx.doi.org/10.1021/acs.joc.0c01564 |