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Counterion Enhanced Organocatalysis: A Novel Approach for the Asymmetric Transfer Hydrogenation of Enones

We present a novel strategy for organocatalytic transfer hydrogenations relying on an ion‐paired catalyst of natural l‐amino acids as main source of chirality in combination with racemic, atropisomeric phosphoric acids as counteranion. The combination of a chiral cation with a structurally flexible...

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Detalles Bibliográficos
Autores principales: Scharinger, Fabian, Márk Pálvölgyi, Ádám, Zeindlhofer, Veronika, Schnürch, Michael, Schröder, Christian, Bica‐Schröder, Katharina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7507862/
https://www.ncbi.nlm.nih.gov/pubmed/32999691
http://dx.doi.org/10.1002/cctc.202000414