Cargando…
Counterion Enhanced Organocatalysis: A Novel Approach for the Asymmetric Transfer Hydrogenation of Enones
We present a novel strategy for organocatalytic transfer hydrogenations relying on an ion‐paired catalyst of natural l‐amino acids as main source of chirality in combination with racemic, atropisomeric phosphoric acids as counteranion. The combination of a chiral cation with a structurally flexible...
Autores principales: | Scharinger, Fabian, Márk Pálvölgyi, Ádám, Zeindlhofer, Veronika, Schnürch, Michael, Schröder, Christian, Bica‐Schröder, Katharina |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7507862/ https://www.ncbi.nlm.nih.gov/pubmed/32999691 http://dx.doi.org/10.1002/cctc.202000414 |
Ejemplares similares
-
Chiral Phosphoric Acids as Versatile Tools for Organocatalytic Asymmetric Transfer Hydrogenations
por: Pálvölgyi, Ádám Márk, et al.
Publicado: (2021) -
Counterion-Enhanced
Pd/Enamine Catalysis: Direct Asymmetric
α-Allylation of Aldehydes with Allylic Alcohols by Chiral
Amines and Achiral or Racemic Phosphoric Acids
por: Pálvölgyi, Ádám Márk, et al.
Publicado: (2020) -
Photocatalyst-free hydroacylations of electron-poor alkenes and enones under visible-light irradiation
por: Pálvölgyi, Ádám Márk, et al.
Publicado: (2022) -
Sterically Demanding Flexible Phosphoric Acids for Constructing Efficient and Multi‐Purpose Asymmetric Organocatalysts
por: Scharinger, Fabian, et al.
Publicado: (2022) -
Selective Hydrogenation of Aldehydes Using a Well‐Defined Fe(II) PNP Pincer Complex in Biphasic Medium
por: Weber, Stefan, et al.
Publicado: (2018)