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Isocyanate Insertion into a La–P Phosphide Bond: A Versatile Route to Phosphaureate-Bridged Heterobimetallic Lanthanide–Coinage-Metal Complexes
[Image: see text] A new route to heterobimetallic lanthanide–coinage-metal complexes is disclosed. The selective insertion of organic substrates such as phenyl iso(thio)cyanate into the La–P bond of the primary phosphido complex (PN)(2)La(PHMes) (1) (with PN(–) = (N-(2-(diisopropylphosphanyl)-4-meth...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7509844/ https://www.ncbi.nlm.nih.gov/pubmed/32885972 http://dx.doi.org/10.1021/acs.inorgchem.0c01971 |