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Isolation of a Homoleptic Non-oxo Mo(V) Alkoxide Complex: Synthesis, Structure, and Electronic Properties of Penta-tert-Butoxymolybdenum
[Image: see text] Treatment of [MoCl(4)(THF)(2)] with MOtBu (M = Na, Li) does not result in simple metathetic ligand exchange but entails disproportionation with formation of the well-known dinuclear complex [(tBuO)(3)Mo≡Mo(OtBu)(3)] and a new paramagnetic compound, [Mo(OtBu)(5)]. This particular fi...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7517713/ https://www.ncbi.nlm.nih.gov/pubmed/32847348 http://dx.doi.org/10.1021/jacs.0c07073 |